basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. Conductometry DR. . 3Principle The main principle involved in this method is that the movement of the ions creates the electrical. Conductometry-. Introduction. Ohm’s law. Conductometric measurements. Factor affecting conductivity. Application of conductometry. tometric titration.

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Conductometry – Wikipedia

Confuctometry amine reacts with the nitrous acid to form nitrosamine, which is followed by the tautomerisation and the water molecule is lost to form the diazonium….

Conant and Hall in described the behaviour of bases in glacial acetic acid. The weak acid such as acetic acid is titrated with the strong base such as sodium hydroxide. Please help improve this article by adding citations to reliable sources. Explain the concept of cell constant.


Potassium chloride is titrated with the precipitating agent such princciple the silver nitrate solution. The basicity is defined as the number of carboxylic acid groups attached to the molecules.

The excess addition of the NH 4 OH does not show the change in the conductivity. Nehmat Sandhu 10 November at Conductometry has notable application in analytical chemistrywhere conductometric titration is a standard technique.

  ITTC 1957 PDF

Explain the concept of molar conductivity. Then it shows the gradual increase in the conductivity by the addition of excess titrant. In this method, the two end points are observed.

This shows the decrease in the conductivity.

The concentration of the solution is inversely proportional conductojetry the conductivity of the sample solution. Then these electrodes are repeatedly washed with the distilled water and finally with the conductivity water.

Conductive measurements began as early as the 18th century, when Andreas Baumgartner noticed that salt and mineral waters from Bad Gastein in Austria conducted electricity. These are carried out as same as the acid—base titrations by using non-aqueous solvents.

The titration curve can be used to graphically determine the equivalence point. The conductivity is inversely proportional to the size of the ions. The conductance is defined as the reciprocal of the resistance.

In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric titrationwhile the term conductimetry conductometryy used to describe non-titrative applications.

2. Conductometry – Pharmaceutical Analysis [Book]

Then the plot between the conductivity and the volume of the titrant shows the plateau. Then conductivity increases slightly up to the equivalence point volume, due to contribution of pfinciple salt cation and anion. These conductivity cells are made up of glass.


This method is first used in the determination of dyes. The acetic acid is dissociated and it combines with the ammonium ion after dissociation of the ammonium hydroxide.

In other words, it is defined as the reciprocal of the princjple. What are the different methods of conductivity measurements? From Wikipedia, the free encyclopedia. For each amount of NaOH added equivalent amount of hydrogen ions is removed. The conductometric titration curve is a plot of the measured conductance or conductivity values as a function of the volume of the NaOH solution added.

Initially the plot shows coneuctometry decrease in the conductivity and then shows the increase in the conductivity. Conductometry was further improved with the development of the glass electrode, which began in This type cell is mainly used for the measurement of the low conductance.

No need for the specific conductivity.